acetoxypalladation
English edit
Noun edit
acetoxypalladation (plural acetoxypalladations)
- (organic chemistry) A reaction in which an acetoxy group and a palladium atom are attached across a double bond (typically as the first step in another reaction)
- 2015 July 22, Javier Mazuela, Debasis Banerjee, Jan-E. Bäckvall, “Palladium(II)-Catalyzed Tandem Oxidative Acetoxylation/ortho C–H Activation/Carbocyclization of Arylallenes”, in Journal of the American Chemical Society[1], volume 137, :
- Measurements of deuterium kinetic isotope effects suggest that C–H bond breaking is not the rate-limiting step and that the acetoxypalladation of the allene moiety is the first irreversible step.